Welcome to our research page!

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We will merge fundamental design principles from synthetic inorganic and organic chemistry, organometallic catalysis, and chemical engineering to manipulate the electronic structures of coordinatively unsaturated metal ions in both molecular complexes and extended porous materials, toward advancing catalysis, separations, and material processability. In particular, we are interested in designing transition metals with unusual electron counts and coordination environments to explore their propensity for new bond activations and transformations.

 

Our current research interests fall broadly into four separate categories:

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Metalloenzyme Mimicry with High-Fidelity Models. Metalloenzymes offer compelling inspiration to conduct challenging chemical transformations. Our research focuses on high-fidelity models of radical S-adenosylmethionine enzymes/alkylcobalamin enzymes (e.g., TokK), which enable selective C(sp³)–H alkylation. Of particular excitement from this enzyme is the opportunity to homologate simple alkanes, include opportunities for the elaboration of methane to ethane. We are further interested in emulating the carbon-based primary coordination sphere of FeMoco, toward small molecule activation with relatively oxidized species.

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Unusual Electronic Structures. Using bespoke ligand scaffolds with ample steric protection, we aim to construct molecules of nontraditional electronic structures, toward establish new frontiers in coordination chemistry. Our research focuses on the 3d transition metals with unusually low coordination numbers.​

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Enhanced Processability of Sorbents. While solid microporous materials have emerged as leading candidates for a wide range of gas separation and storage applications, their structural fragility and powder-like nature limit their practical utility. Our research focuses on the design of sorbents with enhanced processability, including metallomesogenic chemisorption, microporous metallopolymers, and high-performance mixed-matrix membranes. Select targeted separations include oxygen removal from air and the capture and functionalization of carbon dioxide.

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​Unusual Mechanisms of Gas Separations and Storage. Inspired by the reactivity of small molecules mediated by molecular catalysts, we aim to translate the design principles of organometallic chemistry into the realm of selective adsorption. The extensive molecular literature offers a robust foundation to guide the development of alkane-selective adsorbents, multi-gas binding platforms for small molecules such as hydrogen, and new sorbents capable of isotope separations under ambient conditions.

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Please check out updates to our research page for details on our program!